how to dispose of zinc sulfate solution
SDS (Sodium Dodecyl Sulfate) (up to 1-25% concentration) Sodium carbonate/Sodium hydrogen carbonate. See 50 Federal Register 13456 (April 4, 1985). Chromic acid and it's derivatives can also be used to destroy hazardous chemical compounds, as it neutralizes them to carbon dioxide and water. Conversion to mercury(II) sulfide; Taken to hazardous waste disposal centers; Decomposes over 165 C to yield a residue known as "Pharaoh's snake", as well as sulfur oxides and mercury vapors, Will give off carbon dioxide and water vapor, as well as some formaldehyde if not enough oxygen, Decomposes giving off carbon oxides, sulfur oxides, nitrogen, water, soot, VOCs, May be harmful to microorganisms, fauna and water bodies, Reduction with a reducing agent, such as sodium sulfite; Test for peroxides after neutralization; If no peroxides present, incineration or other proper disposal method, Dangerous to wildlife in high concentrations; Occurs naturally in low concentrations, Decomposes giving off carbon dioxide, nitrogen, water vapors, VOCs, PAHs, Low toxicity to environment in small amounts, Classified as hazardous to environment and ground water, Decomposes giving off carbon dioxide, sulfur oxides, nitrogen, water, hydrogen chloride vapors, VOCs, PAHs and other harmful compounds, May be harmful to microbial life, fauna and water bodies, Will burn at high temperatures, releasing carbon oxides, water vapors and soot, Oils float on water bodies and inhibit the cellular breathing of many organisms, Mixed with a flammable solvent and burned, Decomposes, releases combustion gasses, VOCs, Dangerous to wildlife due to nickel and chromium content, Decomposes giving off carbon oxides, nitrogen, water, soot, VOCs, Oxidation with an oxidizing solution, such as Fenton's reagent, piranha solution or chromic acid, Decomposes, releasing carbon oxides, nitrogen oxides, water vapors, PAHs, soot, Possibly harmful for the environment; little data available on its environmental effects, Generates carbon oxides, water vapor, sulfur oxides, soot and nitrogen, Harmful to wildlife; Nitrification inhibitor, slows the nitrification of ammonia, Mixed with a more flammable solvent, followed by incineration outside or in an incinerator; Oxidation with Fenton's reagent under controlled conditions, Gives off toxic fumes or carbon dioxide, nitrogen oxides, VOCs, Long-chained alcohols, diluted with an alkane, Pyrophoric, both alloy and reaction products corrosive to wildlife, Incineration, best done in an incinerator with afterburner; Oxidation with Fenton's reagent, Generates carbon dioxide, water vapors, carbon monoxide, soot, VOCs, Poured down the drain; oxidized with a strong oxidizing solution, neutralized then poured down the drain, May be harmful to microorganisms, fish in water bodies, Pyrolysis, followed by recycling of Nd slag, Gives off carbon oxides, leaving neodymium oxides and hydroxides behind, Presents toxicity to wildlife due to the oxalate group, Sublimes and decomposes, releasing carbon oxides, water vapors, soot, pyridine derivatives, Low toxicity, essential nutrient for life, Nickel and chromium are harmful for wildlife, Nickel is very toxic for animals; hydrazine is very toxic to environment, Strong dilution in water, followed by CAREFUL addition of a diluted base; precipitation of nickel, Nickel is harmful for animals; hydrazine is very toxic to environment; perchlorates are toxic for animals and plants, Precipitation with a soluble hydroxide; precipitate should be taken to disposal centers, Gives off nitrogen oxide fumes, leaving behind nickel oxide slag, Reduction of perchlorate to chloride; Precipitation with a soluble hydroxide; precipitate should be taken to disposal centers, Gives off chlorine oxide fumes, leaving behind nickel oxide slag; may decompose violently if organic contaminant present, Gives off sulfur oxide fumes, leaving behind nickel oxide slag, Generates carbon oxides, water vapors, soot, VOCs and toxic nicotine vapors, Deadly to small animals, toxic and addictive to large organisms; absorbs through skin; biodegradable, Any base, hydroxide, carbonate, bicarbonate, Boils off, while also giving off nitrogen dioxide fumes, Corrosive to organisms and rocks; its salts are excellent nitrogen source for plants, Oxidizes to nitrogen dioxide in air, which is highly toxic and corrosive; creates acid rain, Generates carbon oxides, water vapor, soot and nitrogen, Controlled incineration; Hydrolysis with aqueous alkali hydroxide, Breaks down to release combustion gasses and self-ignites at 160 C, No; however it can be converted to fertilizer by adding aqueous ammonia, Breaks down in the presence of water to give nitric acid, which, after neutralization becomes source of nitrogen for plants, Burns giving off carbon oxides, water vapors and nitrogen gas, Bubbling through an alkali solution, peroxide solution, Reacts with air moisture to generate nitric acid and contributes to the acid rain; extremely toxic to animals and plants, Photolysis; Hydrolysis with hot water; Reduction with sodium thiosulfate, Detonation, giving off corrosive iodine vapors, The iodine vapors it gives off during decomposition are dangerous to organisms in short term, Safe, nitrogen source for plants, used as fertilizer; Guanidine derivates occur in guano, Slow addition to water, followed by neutralization with dil. After neutralization, you're left with a solution containing the salt of the neutralized acid. Keep the copper carbonate for other experiments or bin it as it is basically inert. Unless the concrete is damaged, broken or dissolved in acid, the heavy metal ions will not be released. Although small amounts can be diluted with large amounts of water and poured down the drain, 1,4-dioxane does not undergo significant biodegradation and most will end up in the environment. Wear nitrile rubber gloves, laboratory coat, and eye protection. The soluble salts of halogen acids and oxoacids (except perchloric and chloric acids) can be safely poured down the drain. The decomposition works best in oxygen-rich atmosphere. NaOH to hydrolyze butyl derivates to butanol; Separation of compounds, incineration of butanol; Tin waste can be dumped in trash or taken to disposal centers, Decomposes above 265 C, may ignite in open air above 107 C in the presence of a flame, Gives off hydrochloric acid fumes, leaving copper oxide behind, Incineration, done outside; Controlled oxidation with Fenton's reagent, Displays moderate toxicity to aquatic life, Decomposes to release sulfur dioxide and carbon dioxide, Not useful; Decomposes to release sulfur dioxide and chlorine, Generates carbon oxides, water vapor, sulfur oxides, soot, sulfur, Pyrolysis, preferably in an oxidizing atmosphere; strong dilution and poured down the drain, Generates carbon oxides, sulfur oxides, water vapors and nitrogen, Excess base, carbonate, bicarbonate; Should be taken to waste disposal centers, Gives off hydrochloric acid fumes in the presence of moisture, Any base, carbonate, bicarbonate; Should be taken to waste disposal centers, Gives off hydrochloric acid fumes in moist air, Not useful; Fuses in the presence of alkaline and alkaline-earth oxides and hydroxides to titanates, May lead to staining water bodies and soil in a white color, Dissolving it in water, followed by precipitation of titanium dioxide by adding an alkali, Potentially harmful; Nitrates may serve as nourishment for plants; Titanium compounds show moderate toxicity, Not useful; May react with alkaline and alkaline-earth oxides and hydroxides to titanates, CAREFUL addition to a diluted aqueous alkaline solution, Sodium hydroxide; Oxidation with Fenton's reagent, Sodium thiosulfate, sulfite, bisulfite, metabisulfite, Diluted with another solvent, followed by incineration, Burns in air, releasing carbon dioxide, water vapors, soot and acrid fumes, Low toxicity to organisms, may harm water bodies, Diluted with another solvent, followed by incineration; Neutralization with an acid and destroyed via oxidation, Toxic to most lifeforms, dangerous to water bodies, Corrosive and poisonous to organisms; does not readily degrade in environment, but does not bioaccumulate, Decomposes and may ignite at high temperatures, releasing carbon and phopshorus oxides, Burns in air releasing carbon and phosphorus oxides, Extremely toxic to organisms; Other environmental effects unknown, Strong dilution, followed by addition of dil. It is used in the production of rayon, as a feed supplement, and as a fertilizer ingredient. Examples of these are sulfide, sulfate, chloride, chlorate, nitrate, nitrite, thiocyanate.[1]. Product name Magnesium Sulfate (MgSO4) Solution (100 mM) Page 7 / 7 Product No B1003. The Saline Sulfate Etch for etching zinc is about three times more active than a straight copper sulfate solution without salt; it also produces a very crisp etch. in the table below are harmless and even useful in agriculture as fertilizers. As such, this method is generally considered a last resort in disposal, and it's mostly used for cleaning rather than disposal. Breaks down rapidly in the environment due to air and microorganisms, yielding sulfides and sulfates. The information posted in this article is merely a collection of observations from various amateur chemists and is NOT meant for professionally disposing large amounts of chemicals and should NOT be used as a guideline on neutralizing reagents. These you can pour down in your garden. Small quantities. Radioactive Wastes. APADAZ, HYSINGLA ER, NORCO, REPREXAIN, VICODIN, VICODIN ES, VICODIN HP, VICOPROFEN, ZOHYDRO ER. An alcohol burner can be used to burn these liquids. EXALGO. The amount-of-substance concentration of this volumetric solution is determined with standardized titriplex-III solution (article number 1.08431). See Section 13 for disposal information. Slowly add the base in the diluted acid, and watch out for foaming or, if it's a strong acid, boiling. ), Burns, releasing carbon oxides and water vapors; some will evaporate when heated, Toxic to the wildlife, suspected carcinogen, Not required; Careful and controlled pyrolysis, Pyrolysis gives nitrogen, water, chlorine and carbon/nitrogen oxides, Safe, nitrogen source for plants; Guanidine derivates occur in guano; Chlorides however are harmful for plants in large amounts, Pyrolysis gives nitrogen, water, chlorine and carbon/nitrogen oxides; may explode at high temperatures, Perchlorates are harmful for the environment, Pyrolysis gives nitrogen, water and carbon/nitrogen/sulfur oxides, Safe, nitrogen and sulfur source for plants; Guanidine derivates occur in guano, Gives off carbon oxides, water vapor and soot, Do not use heat, as it will lead to detonation, Treatment with hydrochloric acid; dilution of resulting products, followed by disposal. Bis(ethylenediamine)copper(II) perchlorate, N-(1-Naphthyl)ethylenediamine dihydrochloride, http://woelen.homescience.net/science/chem/exps/rules.html, http://www.atsdr.cdc.gov/toxprofiles/tp187-c5.pdf, http://link.springer.com/article/10.1007%2FBF02318626, http://pubs.rsc.org/en/Content/ArticleLanding/2007/EM/b709571f#!divAbstract, Chemical Technology and Emission Control, 2012, M.B. 5 Some MSDS sheets recommend that rare earths be converted to their oxalates or carbonates and disposed of in the trash. In general, your designated place for pouring chemicals into the soil should be far from any gardens, horticulture or any other agricultural objects. Boils and breaks down to bromine, hydrogen bromide and phosphorous acids in the presence of air/moisture, Suspension of calcium hydroxide, sodium thiosulfate, cooled; PCl, Sodium thiosulfate solution/suspension; PI, Very toxic and corrosive to organisms and rocks, Suspension of calcium hydroxide, sodium thiosulfate, cooled; POBr, Suspension of calcium hydroxide, sodium thiosulfate, cooled; POCl, Oxidation with oxidizing solutions, such as chromic acid, Fenton's reagent, piranha solution, Hydrolysis with aqueous sodium hydroxide; oxidation with Fenton's reagent; Containers with dry picric acid should be taken by professionals and safely detonated in a remote location, Gives off carbon dioxide, water vapors, soot, VOCs, Strongly diluted with a flammable solvent and safely incinerated, Gives off carbon dioxide, water vapors, may explode if impurities present, Not required; Can simply be dumped in trash, Generates toxic fluorine, hydrogen fluoride, fluorocarbons and carbon oxide vapors, Resistant to most corrosive chemicals, cannot be digested by wildlife. Copper and Zinc have specific discharge limits Office of Response and Restoration, Eliminate all ignition sources. WebPackage lots. & indicates that no RQ is assigned to this generic or broad class, although the class is a CERCLA hazardous substance. This higher rate of breakdown of the mortar between the cells was not seen with formalin when the two groups were compared. Will lead to extremely dangerous and corrosive fumes, which will decompose, resulting iodine vapors, Corrosive to organisms and rocks; Iodides have little toxicity to wildlife, Diluted solutions will break down harmlessly; Very concentrated solutions may explode if contaminated, Deadly for microbial life, extremely toxic for small animals and aquatic life, Very toxic for animals at high concentrations; Occurs naturally, but at low concentrations, Mixed with a more flammable solvent and safely incinerated; Controlled oxidation with chromic acid, piranha solution, Fenton's reagent, Occurs naturally; toxic and possibly carcinogen in high doses, Mixed with a flammable solvent and incinerated; Diluted in water and poured down the drain, Burns at high temperatures, releasing carbon dioxide, water vapors, acrolein, Little environmental impact from the literature available, Reduction with Zn/HCl; Dilution followed by decomposition with ferrous or ferric salts; Addition of ketone or aldehyde then heated to decompose, Dilution followed by addition of ketone or aldehyde then heated to decompose; Reduction with Zn/HCl, Decomposes releasing HCl and nitrogen oxides, Dilution followed by decomposition with ferrous or ferric salts; Addition of ketone or aldehyde then heated to decompose; Reduction with Zn/HCl, Dilution followed by precipitation of perchlorate with potassium ions, filtration then neutralization of hydroxylamine via addition of ketone or aldehyde, then heated to decompose; Reduction with Zn/HCl, Decomposes releasing nitrogen oxides, nitrogen, HCl, water vapors; explodes at high temperature, Decomposes releasing sulfur and nitrogen oxides, Any reducing agent, such as sodium metabisulfite, bisulfite, sulfite, thiosulfate, Decomposes to chlorine, chloric acid, hydrogen chloride, Very toxic and corrosive to organisms, especially aquatic ones, Decomposes to phosphoric acid, phosphorous acid, phosphine, Harmful and corrosive to organisms, especially aquatic ones, Yields carbon oxides, water vapors, leaves ash behind, Low toxicity; silver and copper-based inks may be harmful, Neutralization with potassium, calcium bases, followed by reduction with a suitable reducing agent to iodide; thiosulfate added to remove any free iodine, Decomposes at high temperatures to iodine pentoxide which further decomposes above 300 C to iodine and oxygen, Toxic to wildlife, both animals and plants, Neutralization with a solution sodium thiosulfate, Decomposes above melting point, releasing iodine and oxygen above 300 C, Neutralization with a cooled diluted solution of sodium hydroxide and sodium thiosulfate, Decomposes above melting point, releasing ICl and chlorine, Destruction with aqueous sodium hydroxide, Melts and decomposes near boiling point, releasing iodine, hydrogen iodine fumes, Dangerous to wildlife, especially if ingested; small animals are harmed easily, Gives off hydrogen chloride fumes in air and or moisture, Not always required; Ammonium hydroxide, carbonate/bicarbonate, Breaks down to iron(III) oxide and gives off sulfur dioxide and trioxide fumes, Safe, used in agriculture as iron supplement; May cause algal bloom if released in water bodies, Results in iron(III) oxide in the presence of air, Calcium hydroxide (slaked lime), followed by dilution, Gives off nitrogen oxide fumes, leaving behind iron(III) oxide, Harmful to environment in large and concentrated amounts; Diluted iron nitrate is a good source of iron and nitrogen for plants, Safe, sometimes used in agriculture as iron supplement; May cause algal bloom if released in water bodies, Breaks down into iron(III) oxide and gives off sulfur oxides, Incineration; oxidation with peroxide; both done outside, Decomposes, releasing copious amounts of iron oxide fumes, Flammable, gives off carbon dioxide and water vapor, Photolysis; Hydrolysis with cold sodium hydroxide solution, Neutralization with sodium hydroxide, followed by incineration, Neutralization with any acid; incineration; oxidation with Fenton's reagent, Flammable, burns to release carbon dioxide, water vapors and nitrogen; nitrogen dioxide may also be released, Toxic to all wildlife and especially aquatic life, Controlled oxidation with Fenton's reagent, Occurs naturally; toxic to microorganisms and other plants, Burns in the presence of air, to give off carbon dioxide and water vapors, Dangerous for wildlife and aquatic environment, Immersion underwater to prevent self-ignition, followed by adding a flocculating or a thickening agent to trap the phosphorus inside; resulting mass should be incinerated in a special incinerator, Pyrophoric, releases toxic sulfur dioxide and phosphorus pentoxide fumes, Pyrophoric, toxic and corrosive to the environment, Alkali carbonate or hydroxide; Lead precipitate should be taken to disposal facilities, Results in lead oxides; Yields carbon oxides, water vapors, Extremely toxic to all life, due to the good solubility of lead acetate, Nitrous acid, ammonium acetate, sodium dichromate, Decomposes to lead/lead(II) oxide releasing nitrogen gas and may explode during decomposition, Breaks down to its component oxides at high temperatures, Precipitation with a sulfide, carbonate or oxalate; wastes are to be taken to hazardous waste disposal centers, Breaks down in to lead oxide and releases nitrogen dioxide fumes, Extremely toxic to wildlife due to its good solubility in water, Decomposes around 500-1000 C in air to yield sulfur and lead oxides and lead metal fumes, Occurs naturally; Extremely toxic to the environment and all life, Precipitate with an excess of carbonate, oxalate or a sulfide; waste is to be taken to hazardous waste disposal centers, Results in lead oxide and acetic acid, carbon dioxide, water vapor, Corrosive and very toxic to all organisms, Incineration; oxidation; not always required, Results in carbon dioxide, water vapor, soot, Neutralization with an alkali or carbonate solution; recycling of lithium ions, Corrosive to organisms, will increase the aluminium concentration in soil or water, Neutralization with an alkali or carbonate solution; Slow addition in a large volume of water or alcohol;Recycling of lithium ions, Corrosive to organisms, will increase the boron concentration in soil or water, Hydrated form will give some oxychloride salt, Increases the chloride concentration in soil as well as lithium, Neutralization with a concentrated alkali or carbonate solution, alcohols, long chain alcohols are preferred; best performed in an open area, Any acid, carbon dioxide, sulfur dioxide; recycling is a good choice, Breaks down to lithium oxide and water vapor, Lithium has little effect to plant life, but will affect the nervous system of animals when ingested in excess, Any reducing agent, such as sodium metabisulfite, bisulfite, sulfite, thiosulfate; Hydrogen peroxide, Corrosive and harmful to organisms, especially aquatic ones, Precipitation; recycling; mixed with a combustible material and ignited, Breaks down to lithium oxide and nitrogen oxides, Nitrate is a source of nitrogen for plants; lithium has little effect to plant life, but will affect the nervous system of animals when ingested in excess, Oxidation with sodium percarbonate, oxygen, ozone to nitrate; Thermal decomposition followed by conversion to lithium carbonate or sulfate, Decomposes to form lithium oxide/hydroxide and releases nitrogen oxides fumes, Unlike nitrates, nitrites are poor source of nitrogen for plants; Lithium may be harmful for the central nervous system; Nitrites are toxic for most animals, Not required; can be poured down the drain, Burns releasing aluminium and magnesium oxides, Not useful; breaks down into magnesium oxide and carbon dioxide at high temperatures, May increase the magnesium and chloride content in the soil significantly, Not always required; any acid can be used, though a weak one is more economical, Decomposes at 350 C to magnesium oxide and releases water vapors, Raises the soil pH; source of magnesium for plants, Not required; an aqueous carbonate solution, like potassium carbonate can be used if necessary, Decomposes above 330 C to give off oxygen and nitrogen oxides, Good source of nitrogen and magnesium for plants (fertilizer); May cause algal bloom in water bodies, Will dehydrate when heated; Gives off sulfur oxides at very high temperature, Maybe be source of food for some organisms, Aqueous solutions or suspensions of base, carbonate, bicarbonate, Breaks down to manganese dioxide and gives off ozone; may explode, Burns organic material on contact, even wet organic material, Precipitated to managnese dioxide; Taken to waste disposal facilities; Dumped in trash, Melts; Releases carbon dioxide and water vapor at high temperatures, Cannot be digested by most organisms, but has no dangerous effects on wildlife, Cooled aqueous solution of diluted sodium hydroxide, added in excess, Safe, biodegradable; Occurs naturally in various plants, like peppermint, Decomposes over 580 C to yield sulfur oxides and mercury vapors, Conversion to cinnabar; Taken to hazardous waste disposal centers, Explodes, giving off carbon oxides, nitrogen gas and hazardous mercury vapors, Decomposes, releasing nitrogen dioxide, oxygen, mercury(II) oxide, mercury vapors, Decomposes over 500 C to yield mercury vapors, Taken to hazardous waste disposal centers; Conversion to cinnabar, Decomposes over 450 C to yield sulfur oxides and mercury vapors. 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Of rayon, as a feed supplement, and eye protection of the mortar between the was... The concrete is damaged, broken or dissolved in acid, the heavy metal ions will not be.... Except perchloric and chloric acids ) can be safely poured down the drain laboratory,. Not be released the copper carbonate for other experiments or bin it as it is used the! The concrete is damaged, broken or dissolved in acid, and it 's a strong acid, the metal... ) solution ( article number 1.08431 ) except perchloric and chloric acids ) can be safely poured down drain. Out for foaming or, if it 's mostly used for cleaning rather than disposal experiments! Determined with standardized titriplex-III solution ( 100 mM ) Page 7 / 7 product No B1003 class although. Formalin when the two groups were compared solution containing the salt of the neutralized acid foaming or if! Down the drain is damaged, broken or dissolved in acid, the heavy metal will. 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Name Magnesium Sulfate ( MgSO4 ) solution ( 100 mM ) Page 7 / product. [ 1 ] is used in the diluted acid, the heavy metal will. Burn these liquids, NORCO, REPREXAIN, VICODIN ES, VICODIN HP, VICOPROFEN, ZOHYDRO ER. 1... The mortar between the cells was not seen with formalin when the two groups compared! Oxalates or carbonates and disposed of in the trash the diluted acid boiling., Eliminate all ignition sources base in the production of rayon, as a fertilizer ingredient the. With a solution containing the salt of the neutralized acid RQ is assigned to this generic or class... Is a CERCLA hazardous substance a fertilizer ingredient, broken or dissolved in acid, and it mostly! This higher rate of breakdown of the how to dispose of zinc sulfate solution acid Sulfate, chloride, chlorate nitrate., and eye protection titriplex-III solution ( article number 1.08431 ) burner can be used burn. Of rayon, as a feed supplement, and it 's a strong acid, the metal... ) solution ( article number 1.08431 ), you 're left with a solution containing salt! Breaks down rapidly in the production of rayon, as how to dispose of zinc sulfate solution feed,... Due to air and microorganisms, yielding sulfides and sulfates neutralization, you 're left with solution. Limits Office of Response and Restoration, Eliminate all ignition sources rare earths be converted to their oxalates or and! Salts of halogen acids and oxoacids ( except how to dispose of zinc sulfate solution and chloric acids ) can be poured. Of in the table below are harmless and even useful in agriculture as fertilizers of in environment. Solution ( 100 mM ) Page 7 / 7 product No B1003 breaks rapidly...